Microsoft 365 features that help users manage their subscriptions, account settings, and billing information.
Dear @David Gannon,
Thank you for posting your question in the Microsoft Q&A forum.
Please understand that our forum is a public platform, and we will modify your question to cover your organization domain name in the description. Please notice to hide these personal or organization information next time you post error or some information to protect personal data.
Based on your description, the Office product key has already been redeemed and linked to the former employee’s Microsoft account, so it cannot be reassigned directly on the device. For one-time purchase versions of Office, the license becomes permanently associated with the Microsoft account used during the initial activation. This means re-entering the same key under a different account will not work.
However, if this is urgent, you can try to contact Microsoft Support team and request a license transfer due to employee departure, and provide: Product key, Proof of purchase or Business ownership details.
You can use this link to find the appropriate contact number: Global Customer Service phone numbers - Microsoft Support
Note: Please understand that as forum moderator, my primary goal is to provide helpful guidance and support through general troubleshooting steps. While I don’t have access to internal systems or test devices required to resolve backend issues, I truly appreciate your understanding of these limitations. I genuinely hope the information I share helps guide you in the right direction, and I'm always here to assist as much as I can within my scope.
I hope information above helpful. If you have any other questions, please feel free to reach out.